They almost always go hand in hand, the few instances I can think of where they don't involve either obsession approaching madness, subtle and sneaky corruption, or turned victims.
Like the good man who delves dark arts to try and resurrect his beloved wife, totally going off the rails into dark magics that shouldn't be trifled with until they eventually succumb.
or
The Magician who exposes his apprentice to evil, while hiding the fact it's evil from him. "Yes, now sacrifice the frog and repeat after me.". The apprentice is led down the big E path without knowing what they're getting into, based on misplaced trust their master is teaching them, not corrupting them with taint.
or
The Vampire food source who through constant exposure goes Stockholm syndrome and "loves" their master, happily drinking in their tainted blood as a reward. I dunno that that's really little e evil, since they've been conditioned and forced into it to the point where free will is gone, they're just a victim, though they've been corrupted with taint, so they are big E Evil.
Though, I guess, eventually the obsessive husband, the corrupted apprentice and the bloodbound thrall probably cross over into evil acts due to the influence of their Evil taint, so that stage of being Evil but not evil is transient. (and strangely seems to be the case just as the PCs arrive on the scene to wrestle the moral ambiguities for the amusement of the GM, lol).